  | 
                            “Mantle
                                plumes” are NOT from ancient oceanic
                            crust  | 
                           
                         
                        Yaoling
                            Niu1 &
                            Michael J. O'Hara2 
                           
                          1Durham University,
                          Durham DH1 3LE, UK, yaoling.niu@durham.ac.uk 
                        2University of Wales, Aberystwyth SY23 3DB, mio@aber.ac.uk 
                         
                          1. Introduction 
                        Following the paper by Niu et
                            al. (2002), we point out
                            that there are many more difficulties than certainties in
                            models invoking ancient recycled oceanic crust as
                            the source material for ocean island basalt (OIB).
                            Our paper Niu & O'Hara (2004) titled “Mantle
                            plumes are not from ancient oceanic crust” in
                            the  book Oceanic
                            Hotspots summarises  our
                            work in progress. Our  perspective contrasts
                            with that advanced in the classic paper, published
                            20 years earlier by Hofmann & White (1982),
                            titled “Mantle
                            plumes from ancient oceanic crust”. We
                            published a more comprehensive treatment a year later
                            (Niu & O'Hara,
                            2003) titled “Origin
                            of ocean island basalts: A new perspective from petrology,
                          geochemistry and mineral physics considerations”.
                          It is apparent from reading the papers by Sobolev
                          et al. (2005,
                          2007) on the same subject, that our views
                          have been overlooked.  
                        In
                          this brief webpage, we summarise our views (Niu & O'Hara,
                          2003) in
                          an accessible form for readers. We do not ignore
                          the interesting  issues raised by Sobolev
                          et al. (2005,
                          2007). Figures and page numbers
                          mentioned in the text (e.g.,
                          ECV 5-2) refer to  those in (Niu & O'Hara,
                          2003). 
                        2. Background and context 
                        If we assume the Earth’s
                          primitive mantle (PM) to be compositionally uniform,
                          we must explain why the mantle source for mid-ocean
                          ridge basalts (MORB) is more depleted both isotopically
                          and in terms of incompatible elements than the mantle
                          source for OIB. By interpreting MORB mantle
                          depletion as resulting from continental crust extraction
                          in Earth’s early history (Armstrong, 1968; Gast,
                          1968; Hofmann, 1988), we could be satisfied with the
                          OIB source being less depleted than the MORB source.
                          However, OIB mantle source is not just less depleted,
                          but enriched in incompatible elements relative to the
                          PM. It also varies significantly in inferred abundances
                          and ratios of incompatible elements as well as radiogenic
                          isotopes from one island to another and from one group
                          of islands to another group. Therefore, the mantle
                          source for OIB is heterogeneous on all scales.  
                        By accepting
                              the assumption that
                          the entire mantle is in the solid state and that solid-state
                          elemental fractionation is unlikely (Hofmann
                          & Hart,
                          1978), it is logical to suspect that processes known
                          to occur in the upper mantle and crust (e.g.,
                          partial melting and magma evolution, dehydration, alteration/metamorphism,
                          differential weathering, transport and sedimentation)
                          are the likely causes of elemental fractionation. These
                          shallow or near-surface fractionated materials are
                          then introduced into the mantle source regions of oceanic
                          basalts through subduction zones. Mantle compositional
                          heterogeneity is thus a general consequence of plate
                          tectonics because of crust-mantle recycling. Among
                          many contributions endeavoring to understand the origin
                          of mantle compositional heterogeneity in the context
                          of plate tectonics is the classic paper by Hofmann & White (1982).
                          They proposed that "oceanic crust
                          is returned to the mantle during subduction…
                          Eventually, it becomes unstable (at the core-mantle
                          boundary or CMB; see Christensen & Hofmann, 1994)
                          as a consequence of internal heating, and the resulting
                          diapirs become the source plumes of oceanic island
                          basalts (OIB) and hot spot volcanism." They
                          also stressed that this recycled ancient oceanic crust,
                          the plume material which is the source of OIB, is geochemically
                          more ‘‘enriched’’ in
                          K, Rb, U, Th, and light rare-earth elements relative
                          to the more "depleted" source
                          of MORB. While some details are considered conjectural,
                          the principal idea of the model has, since 1982, been
                          widely accepted by the solid Earth community as being
                          correct, except for those who share the view
                          of Niu & O'Hara (
                          2003). 
                        3. Niu & O’Hara
                              (2003)                          demonstrated
                              that there is no obvious association between ancient
                              recycled oceanic crust and OIB source in terms
                              of petrology, geochemistry, and mineral physics 
                        
                          - 
                            
Melting
                              of oceanic crust with basaltic/picritic compositions
                              cannot produce high-magnesian lavas parental to
                              most OIB. Primitive OIB melts (> 15% MgO) are
                              probably more magnesian than bulk ocean crust (< 13%
                              MgO) (p. ECV 5-2). 
                           
                          - 
                            
" One may argue that
                              OIB are derived from melts of recycled oceanic
                              crusts mixed with predominantly peridotite
                              melts. This is possible and will apparently
                              relax the OIB MgO requirement, but then OIB
                              are no longer derived from recycled oceanic
                              crust alone" (p. ECV 5-2). Note
                              that the original theory by  Hofmann & White                              (1982)
                              and  Christensen & Hofmann (1994) is
                              incompatible with this possible scenario, but by
                              using it  Sobolev
                              et al. (
                              2005, 2007) discovered new evidence in
                              support of  Hofmann & White                              (1982)
                              and  Christensen & Hofmann (1994) without
                              addressing points 3.1 and 3.2 in this list.  
                           
                          - 
                            
Oceanic
                              crust passing through subduction zone dehydration
                              reactions should be depleted in water-soluble
                              incompatible elements such as Ba, Rb, Cs, Th,
                              U, K, Sr, Pb relative to water-insoluble incompatible
                              elements such as Nb, Ta, Zr, Hf, Ti, etc. Residual
                              crust with such trace-element systematics is
                              unsuitable as a fertile source for OIB (Figures
                              2-3;  p.
                              ECV 5-3,4,5).  Melting or partially melting
                              such residual crust will never produce OIB or
                              any volcanic rocks ever sampled on the Earth’s
                              surface. 
                           
                          - 
                            
Ancient oceanic crust is too
                              depleted to produce the Sr-Nd-Hf isotopic signatures
                              of most OIB (Figure 1; p. ECV 5-2,3). 
                           
                          - 
                            
OIB Sr-Nd-Hf isotopes
                              preserve no signals that indicate previous subduction-zone
                              dehydration histories (Figures 4-5; p. ECV 5-5,7,8,9). 
                           
                          - 
                            
Subducted
                              oceanic crust at shallow lower-mantle conditions
                              forms mineral assemblages that are much (>2%)
                              denser than the ambient peridotitic mantle (Figure
                              6; p. ECV 5-9,10). 
                           
                          - 
                            
If subducted crust melts in
                              the deep lower mantle, this melt, depending on
                              its composition, may have still greater (up to
                              15%) density than solid peridotitic mantle. Therefore
                              ancient oceanic crust that has subducted into
                              the deep lower mantle will not return in bulk
                              to the upper mantle in either the solid (see
                              3.6 in this list) or molten state (Figure 7; p.
                              ECV 5-10,11,12). 
                           
                          - 
                            
Small fragments of subducted
                              oceanic crust could be returned to the upper
                              mantle source regions of oceanic basalts provided
                              they are carried along with streams of ascending
                              buoyant material. However, there is no convincing
                              evidence for the presence of bulk subducted crust
                              in the source regions of oceanic basalts, noting
                              points 3.3, 3.4 and 3.5 in this list (p. ECV 5-16). 
                           
                          - 
                            
It is probable
                              that subducting oceanic crust does not penetrate
                              the 660-km discontinuity, but may be stripped,
                              at least partly, off the slab and remain in the
                              transition zone. This may be a result of its lower
                              density compared with the peridotite mantle around
                              660 km (Figure 6; p. ECV 5-16).  This scenario
                              would apparently make recycled oceanic crust a
                              less problematic potential source material for
                              OIB, but this model differs from the CMB-origin
                              model (Hofmann & White, 1982; Christensen & Hofmann,
                              1994).
                              Furthermore, physical difficulties remain. Subducted
                              crust is eclogitic in most of the upper mantle
                              and is probably far too dense to ascend to OIB
                              source regions (p. ECV 5-14). 
                           
                         
                        4. Summary 
                        Models invoking recycled
                          oceanic crust to explain the geochemistry of OIB must
                          be able to: 
                        
                          -  demonstrate how such crust can, by melting, produce
                            high-magnesian lavas in many OIB suites, and
 
                          - explain the lack of subduction-zone dehydration
                            (metamorphic) signatures in OIB.  
 
                         
                        The latter
                            includes: 
                        
                          - 
                            
why OIB are enriched not only in water-insoluble
                              incompatible elements, but also water-soluble incompatible
                              elements, 
                           
                          - 
                            
why OIB are enriched in the progressively
                              more incompatible elements, and 
                           
                          - 
                            
why OIB show
                              significant correlated Sr-Nd-Hf isotopic variations,
                              all of which are magmatic (vs. metamorphic) fingerprints.                             
                           
                         
                        Models that require ancient subducted
                          crust as plume sources reactivated from the lower mantle
                          also require physical mechanisms to overcome the huge
                            negative buoyancy of  subducted crust in both
                          the lower and the upper mantle (p. ECV 5-16) 
                        5. Our perspective of the origin
                            of OIB sources (Niu & O'Hara,
                            2003)  
                        The recycled deep portions of oceanic
                          peridotitic lithosphere are the best candidate for
                          the source feeding hot spot volcanism and OIB. These
                          deep parts of oceanic lithosphere are likely to
                          have been enriched in water-soluble incompatible elements
                          such as Ba, Rb, Cs, Th, U, K, Sr, Pb as well as all
                          other incompatible elements as a result of low-degree
                          melt metasomatism at the interface between the LVZ
                          and the cooling and thickening oceanic lithosphere.
                          These metasomatized lithospheric materials are peridotitic
                          in bulk composition. They can, by partial or locally
                          total melting, produce high-magnesian melts for primitive
                          OIB. Such materials (vs. crustal compositions) will
                          develop positive thermal buoyancy upon heating, if
                          subducted into the deep mantle, especially in the presence
                          of a peridotitic melt phase, making it possible for
                          the bulk material to ascend and feed OIB volcanism. 
                        Concerning the papers by Sobolev
                            et al. (2005,
                            2007), we comment
                          that variations, of
                          the type reported, in Ni, Ca, Mn and Cr content in
                          olivine phenocrysts is a straightforward petrologic
                          consequence of peridotite melting processes and
                          mineral facies changes in the upper mantle. We are
                            investigating the extent to which these effects account
                            for the observations quantitatively. 
                        4. Acknowledgements 
                        We thank Gillian
                        Foulger for inviting this contribution. 
                        References 
                        
                          - 
                            
Armstrong, R. L., A model for
                              the evolution of strontium and lead isotopes in
                              a dynamic earth, Rev. Geophys. Space Phys.,
                              6,
                              175-200, 1968. 
                           
                          - 
                            
Christensen, U. R. & A.
                              W. Hofmann, Segregation of subducted oceanic crust
                              in the convecting mantle, J.
                                Geophys. Res., 99, 19867-19884, 1994. 
                           
                          - 
                            
Gast, P. W., Trace element fractionation
                              and the origin of tholeiitic and alkaline magma
                              types, Geochim. Cosmochim. Acta, 32,
                              1055-1086, 1968. 
                           
                          - 
                            
Hofmann,
                                A. W. & W. M. White, Mantle plumes from ancient
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                                421-436, 1982. 
                           
                          - 
                            
Hofmann, A. W., Chemical differentiation
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                              1988. 
                           
                          - 
                            
Hofmann, A. W. & S. R. Hart,
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                              in the mantle, Earth Planet.
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                          - 
                            
Sobolev,
                              A. V., A.W. Hofmann, D. V. Kuzmin, G. M. Yaxley,
                              N. T. Arndt, S.-L. Chung, L. V. Danyushevsky,
                              T. Elliott, F. A. Frey, M. O. Garcia, A. A.Gurenko,
                              V. S. Kamenetsky, A. C. Kerr, N. A. Krivolutskaya,
                              V. V. Matvienkov, I. K. Nikogosian, A. Rocholl,  I.
                              A. Sigurdsson, N. M. Sushchevskaya & M. Teklay,
                              The amount of recycled crust in sources of mantle
                              derived melts, Science, 20 March 2007 (10.1126/science.1138113). 
                           
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                        last updated 15th
                      April, 2007   |