| 
                           
                            |  | Continental 
                              lithospheric thinning results from hydration weakening, 
                              not “delamination”, and is a special 
                              consequence of plate tectonics |  Yaoling 
                          Niu Durham University, 
                          Durham DH1 3LE, UK, yaoling.niu@durham.ac.uk  1. Terminology 
                          and concepts In recent years, the term 
                          “delamination” [Ed: see Lithosphere 
                          thinning pages, and also Continental 
                          delamination and the Colorado Plateau by P. Bird, 
                          for an explanation of what delamination is and isn't] 
                          has been developed into a model whereby the basal portions 
                          of locally or regionally thickened continental mantle 
                          lithosphere, and possibly also lower crust, sink into 
                          the deeper mantle. Most recently, lithosphere delamination 
                          has been suggested to cause continental volcanism. My 
                          objective in this webpage is to encourage interested 
                          readers to take away the following Q-and-A messages 
                          and to remain skeptical of the proposed mechanism and 
                          deduced consequences of continental lithosphere "delamination". Q: Can subcontinental 
                          lithosphere be thinned?A: It is difficult, but it happens in some places.
 Q: Can it happen by “delamination”?A: It is possible, but extremely difficult and perhaps 
                          unlikely.
 Q: Why is it difficult?A: Because the lithosphere is too buoyant to sink into 
                          the dense asthenosphere.
 Q: How then could the 
                          lithosphere be thinned?A: Its basal portions can be transformed into convecting 
                          asthenosphere.
 Q: How?A: By hydration-weakening.
 Q: Where does the water 
                          come from? A: It comes from recently subducted oceanic lithosphere. 
                          Thus, this method of lithosphere thinning is a special 
                          consequence of plate tectonics.
 Compared with the young 
                          (< 200 Ma) ocean crust, the continental crust is 
                          rather old, on average > ~ 2.5 Ga. This is because 
                          the continental crust is protected by the similarly 
                          old continental lithospheric mantle (CLM) from the underlying 
                          convective asthenospheric mantle (CAM). Since its inception, 
                          much of the CLM (in contrast to oceanic lithosphere) 
                          has been isolated from mantle convection. The protective 
                          power of the CLM arises from its depleted composition 
                          (high Mg/Fe and low Al2O3) and 
                          physical buoyancy relative to the CAM. It is physically 
                          buoyant because it comprises light minerals with high 
                          Mg/Fe, lacking dense garnet due to low Al2O3 
                          etc. It is true that the CAM is hot, whereas the CLM 
                          is cold. However, because of the negligibly small thermal 
                          expansion coefficient (~ 3 x 10-5 K-1 
                          of mantle peridotites), the density contrast due to 
                          the compositional differences (~1%) cannot be overcome 
                          without heating the CLM by ~ 300 K. In other words, 
                          in order to reduce the buoyancy contrast so that the 
                          CLM may sink into the CAM, the CAM must be additionally > 300K 
                          hotter. This is impossible, and therefore, 
                          the CLM cannot delaminate and sink into the dense CAM. 
                          Straightforward arguments of this kind must be considered 
                          when evaluating the likelihood of physical models.  2. Hydration-weakening 
                          and the best example There is evidence that 
                          the CLM has indeed been thinned in some places. One 
                          of the best examples is eastern China in general and 
                          the North China Craton (NCC) in particular. There is 
                          every reason why the CLM root of ancient cratons should 
                          be stable indefinitely, but this is not the case beneath 
                          the NCC. The existence of Paleozoic diamondiferous kimberlites 
                          in the NCC indicates that the eastern China lithosphere 
                          must have been ~ 200 km thick in the Palaeozoic. However, 
                          petrologic studies of Cenozoic volcanism and mantle 
                          xenoliths, as well as seismic studies, show convincingly 
                          that the present-day CLM beneath eastern China is no 
                          more than 80 km thick. Thus, the lithosphere beneath 
                          eastern China must have lost more than 120 km of its 
                          original thickness, probably in the Mesozoic. “Delamination”, 
                          “large scale extension and stretching” and 
                          “thermal erosion by mantle plumes” have 
                          been suggested as the cause. As explained above, however, 
                          the “delamination” process is physically 
                          unlikely. Evidence for extension exists, but it is inadequate 
                          to explain the observations. As a final resort, mantle 
                          plumes were invoked to explain the lithosphere thinning 
                          in eastern China and the intra-plate volcanism there 
                          in the Mesozoic and Cenozoic. However, there is no evidence 
                          of any kind in favor of mantle plumes in the region. 
                          Alternatives are needed. I offered an alternative interpretation 
                          [1], where I suggest that the Mesozoic lithosphere thinning 
                          and Mesozoic/Cenozoic basaltic volcanism in eastern 
                          China are a special consequence of plate tectonics. Mesozoic lithosphere thinning 
                          in eastern China is best explained by a process that 
                          “transformed” the basal portion of the lithosphere 
                          into convective asthenosphere by hydration (Figure 1). 
                          The water required may have come from dehydration of 
                          subducted Pacific (or predecessor) oceanic lithosphere 
                          that is presently lying horizontally in the transition 
                          zone beneath eastern Chinese continent, where it is 
                          detected by seismic tomography [2]. The Mesozoic volcanism 
                          may be genetically associated with the lithospheric 
                          thinning because the basaltic source is ancient isotopically 
                          enriched (εNd < 0; [3]) lithosphere being converted 
                          into asthenosphere (Figure 1).  
 Figure 1: Cartoon illustrating 
                          the concept that continental lithosphere can be thinned 
                          through “hydration-weakening” at its base 
                          [1]. That is, the basal portion of the lithosphere can 
                          be transformed into “asthenosphere” by water-induced 
                          viscosity reduction. In the case of eastern China, the 
                          water may originate from dehydration of subducted Pacific 
                          plate that lies horizontally in the transition zone 
                          [2]. The water probably rises in the form of hydrous 
                          melt although the exact form is unconstrained. The associated 
                          basaltic volcanism would probably have an isotopically 
                          enriched signature (i.e., εNd < 0) that is inherited 
                          from ancient metasomatized lithosphere that is being 
                          transformed into “asthenosphere”. In this 
                          figure, "Continental lithospheric mantle" 
                          is considered to be "cold", rigid, strong, 
                          highly viscous/elastic and isolated from convection. 
                          "Asthenosphere" is considered to be 
                          "hot", soft, weak, less viscous and part of 
                          the convection system.  The NNE-SSW Great Gradient 
                          Line (GGL; Figure 2) marked by sharp altitude, gravity, 
                          crustal thickness and mantle seismic velocity changes 
                          from the plateau in the west to the hilly plains of 
                          eastern China reflects the variation in lithospheric 
                          thickness from probably > 150-200 km thick beneath 
                          the plateaus in the west to probably < 80 km thick 
                          beneath eastern China (Figure 2). The “remote” 
                          western Pacific subduction system “wedge suction” 
                          [1] induces asthenospheric flow from beneath eastern 
                          China towards the subduction zones, which in turn requires 
                          asthenospheric material replenishment from beneath the 
                          western plateaus to eastern China (Figure 3). As a result, 
                          such eastward asthenospheric flow experiences upwelling 
                          and decompression as it passes from beneath thickened 
                          to thinned lithosphere, which causes it to partially 
                          melt and fuel Cenozoic eastern China basaltic volcanism 
                          (Figure 3). Such volcanism may have begun at the end 
                          of the Mesozoic lithosphere thinning in the late Cretaceous 
                          [4].  
 Figure 2: (a) Topographic 
                          map showing a sharp altitude contrast in continental 
                          China as indicated by the blue dashed line. This line 
                          is called the Great Gradient Line (GGL) [1] as this 
                          altitude contrast coincides with contrasts in mantle 
                          seismic velocity (higher in the west than in the east) 
                          at 100-150 km depth, (2) Bouguer gravity anomaly (lower 
                          in the west than in the east), and crustal thickness 
                          (higher in the west than in the east). These consistent/coincident 
                          east-west contrasts are interpreted as the expression 
                          of isostacy – reflecting thin lithosphere in the 
                          east and thickened lithosphere in the west [1]. Lithosphere 
                          thinning in eastern China is generally accepted to have 
                          taken place in the Mesozoic (see Figure 1), but lithosphere 
                          thickening in western China (plateaus) is interpreted 
                          as being genetically associated with the Indian-Asian 
                          collision since the Cenozoic [1].   
 Figure 3: Cartoon showing 
                          asthenospheric flow and Cenozoic volcanism in eastern 
                          China. The lithosphere is thick beneath high plateaus 
                          in western China and thin beneath eastern China (see 
                          Figure 2) across the Great Gradient Line (GGL). Western-Pacific-subduction-induced 
                          “corner-flow” requires asthenosphere replenishment 
                          from the west [1]. In response, the eastward flow of 
                          asthenosphere beneath eastern China requires replenishment 
                          from the west beneath the plateaus. The latter flow 
                          experiences decompression of > 50 km vertically, 
                          which will result in decompression melting and Cenozoic 
                          volcanism in eastern China. As the source is the asthenosphere, 
                          this model explains the isotopic depletion of Cenozoic 
                          volcanism (i.e., εNd > 0). Note, the asthenosphere 
                          flow is driven by a “wedge-suction”-induced 
                          pressure gradient [1], and it is NOT the same as “edge” 
                          convection. This hypothesis, which 
                          requires further testing, is consistent with available 
                          observations and complies with straightforward physics. 
                          The proposed mechanism of lithosphere thinning thus: 
                           
                            does not require 
                              hot mantle plumes beneath eastern China; the horizontally 
                              lying transition-zone slabs [2]act as a cold thermal 
                              boundary layer that absorbs heat from above and 
                              below, thus preventing hot mantle plumes from rising 
                              from the lower mantle and traversing the upper mantle 
                              [1]; 
                            does not require 
                              lithospheric “delamination”, which suggests 
                              that deep portions of the buoyant cratonic lithosphere 
                              sink into the dense asthenosphere – a scenario 
                              that is physically unlikely; 
                             does not 
                              require lithospheric extension/stretching the scale 
                              of which was limited in the Mesozoic; 
                            explains the 
                              lithosphere thinning beneath all of eastern China, 
                              not just the NCC; and thus  
                            questions 
                              the significance of South China continental subduction 
                              as a cause of lithosphere thinning beneath the NCC. 
                             The suggested mechanisms 
                          for Mesozoic/Cenozoic volcanism in eastern China are 
                          consistent with the geochemistry of the basalts [3], 
                          physical scenarios of mantle melting [1] and geophysical 
                          observations [1,2]. The latter principles and observations: 
                           
                            do not favor 
                              a hot mantle plume origin for eastern China volcanism; 
                            do not support 
                              the suggestion of oceanic-ridge-like passive mantle 
                              upwelling and decompression melting because there 
                              is no unambiguous evidence for large-scale rifting 
                              or lithosphere separation in eastern China since 
                              the Mesozoic; 
                            argue that 
                              the eastern China Mesozoic/Cenozoic basins may not 
                              comprise evidence for continental extension and 
                              rifting. These basins may be an isostatic response 
                              [1] to horizontally lying dense slab materials in 
                              the transition zone.  
                          Important points to note are: 
                           
                            the NNE-SSW 
                              GGL (Figure 2) [1] is probably a young feature that 
                              results from Indian-Asian collision since the early 
                              Tertiary; 
                            subduction-zone 
                              dehydration is necessarily incomplete [1,5] because 
                              of formation of stable hydrous phases in subducting 
                              slabs. For example, in the subducting crust, lawsonite 
                              forms. It can contain ~ 11 wt % H2O, 
                              and is stable up to 11 GPa [6], much deeper than 
                              expected subduction-zone dehydration. Importantly, 
                              serpentines within subducting lithospheric mantle 
                              [5] contains up to 13 wt % H2O, and is 
                              stable up to 7 GPa [7] before being transformed 
                              to dense hydrous magnesium silicate phases that 
                              are stable at even greater pressures (~ 5 to 50 
                              GPa [6,8]). This allows water transport to great 
                              depths in the mantle [9]. All these hydrous phases 
                              tend to decompose and form new and less hydrous 
                              phases (e.g., Wadsleyite, < 3.0 wt% H2O; 
                              Ringwoodite, < ~ 2.2 wt% H2O; Mg2SiO4-spinel 
                              is essentially anhydrous) as the temperature increases 
                              [1,6]. The horizontal slabs in the transition zone 
                              beneath eastern China [1,5] experience isobaric 
                              (horizontal movement) heating with time, and will 
                              thus lose water accordingly. The water so released 
                              would form hydrous melts that migrate upwards and 
                              weaken the deep portions of the lithosphere (hydration-weakening) 
                              and transform them into asthenosphere. This gives 
                              rise to the process of lithosphere thinning [1]; 
                            mantle wedge 
                              suction, while less strong than ridge suction [10], 
                              is an important driving force for asthenospheric 
                              flow; 
                            more recent 
                              lithosphere accretion beneath the NCC is a straightforward 
                              consequence of conductive cooling of the asthenospheric 
                              mantle. However, the suggestion that “new 
                              lithosphere replaces old lithosphere” should 
                              be avoided if it is intended to emphasize processes 
                              or physical mechanism because it is misleading. 3. Any other 
                          examples? A literature search readily 
                          reveals that wherever the concept of “lithosphere 
                          delamination” is invoked, oceanic lithosphere 
                          subduction was ongoing either simultaneously or shortly 
                          beforehand. Other examples include the southern Andes, 
                          the western USA, the western Mediterranean and Tibet. 
                          On the other hand, mantle plumes have been proposed 
                          to have impinged or to underlie the African lithosphere, 
                          yet the lithosphere thinning there has only occurred 
                          on limited scale and been associated with active rift 
                          zones or ancient sutures. This suggests that  
                           thermal erosion, if thermal mantle 
                            plumes did indeed exist beneath Africa, is ineffective 
                            in thinning the lithosphere, andthe role of water or hydration-weakening 
                            is indeed the key mechanism – no oceanic lithosphere 
                            subduction is currently ongoing or occurred in the 
                            recent past beneath the African plate. The closest 
                            plate boundaries to the African plate are ocean ridges, 
                            the south Mid-Atlantic Ridge, the Southwest Indian 
                            Ridge, the Central Indian Ridge and the Read sea spreading 
                            centers. A full paper describing 
                          these ideas is presently in preparation, but the basic 
                          concept and discussion can be found in reference [1]. 4. Acknowledgement 
                           I thank Gillian Foulger for inviting this 
                          contribution, and Thomas Duvernay for spotting a typographic error 2nd May, 2018. 
 References 
                           
                            
                           
                            Kárason, 
                              H. & R. van der Hilst, Constraints on mantle 
                              convection from seismic tomography, Geophys. 
                              Monogr., 121, 277-288, 2000 
                            Xu, Y.-G., 
                              Thermo-tectonic destruction of the Archean lithospheric 
                              keel beneath the Sino-Korean Craton in China: Evidence, 
                              timing and mechanism, Phys. Chem. Earth (A), 
                              26, 747-757, 2001 
                            Yan, J., J.-F. 
                              Chen, Z. Xie & T.-X. Zhou, Mantle xenoliths 
                              in Late Cretaceous basalts in eastern Shandong: 
                              New constraints on the timing of Eastern China lithospheric 
                              thinning, Chinese Sci. Bull., 8, 
                              1570-1574, 2003 
                            
                           
                            Williams, 
                              Q. & R.J. Hemley, Hydrogen in the deep earth, 
                              Ann. Rev. Earth Planet. Sci., 29, 
                              365-418, 2001 
                            Ulmer, P. 
                              & V. Trommsdorff, Serpentine stability to mantle 
                              depths and subduction-related magmatism, Science, 
                              268, 858-861, 1995 
                            Frost, D.J., 
                              The stability of dense hydrous magnesium silicates 
                              in earth’s transition zone and lower mantle, 
                              Geochem. Soc. Spec. Publ., 6, 
                              283-297, 1999 
                            Kuroda, K. 
                              & T. Irifune, Observation of phase transformations 
                              in serpentine at high pressure and high temperature 
                              by in situ X-ray diffraction measurements, Geophys. 
                              Monogr., 101, 545-554, 1998 
                            
                           
 Discussion 28th May, 2006, Don AndersonThe term ‘delamination’ has been widely 
                          used for the gravitational removal of the continental 
                          lithosphere. There have been objections to this usage 
                          of the term and it has even been questioned whether 
                          it is possible. The term ’foundering’ has 
                          also been used. There are other ways to remove or thin 
                          lithosphere that involve lateral flow or detachments. 
                          Over-thickened continental crust can also be removed 
                          by mechanisms that do not involve a Rayleigh-Taylor 
                          instability. The term ’delamination’ does 
                          not imply gravitational removal, or lithosphere removal. 
                          To avoid confusion, the term ‘crustal delamination’ 
                          should be used for the removal of lower continental 
                          crust, by whatever mechanism. Gravitational instability 
                          or Rayleigh-Taylor instability or foundering should 
                          be used if a specific mechanism is being treated.
  Lower crustal delamination is quite different 
                          from continental lithosphere removal described by Yaoling 
                          Niu in this page. It is difficult to remove buoyant 
                          cratonic peridotite (SCLM) for the reasons described. 
                          It is not only buoyant; it is strong and has high viscosity, 
                          when cold and dry. Weak or wet peridotite can be removed 
                          by lateral flow. But mafic overthickened arc and convergent 
                          belt lower crust is a different story (Anderson, 
                          2005). The use of the term gravitational instability 
                          or Rayleigh-Taylor instability is misleading. The lower 
                          crust can be removed by a variety of mechanisms and 
                          delamination is a better and more descriptive term. 
                          A laminated solid can be delaminated by peeling, scraping, 
                          bending, faulting, rubbing, erosion or soaking off the 
                          laminations. It is more likely to be a band-aide removal 
                          or Velcro type operation than a gravitational instability 
                          as in fluid dynamics. It is aided by water from an underlying 
                          slab and it is most likely to occur in convergent belts 
                          and in arcs and is therefore related to subduction, 
                          but it is not the same as subduction.  The removal of dense lower crust should 
                          not be confused with, or equated to, continental lithosphere 
                          removal or a fluid dynamic Rayleigh-Taylor or density 
                          instability. There is probably a buoyant refractory 
                          peridotite layer in the shallow mantle (the perisphere), 
                          of which the long-lived subcontinental cratonic root 
                          (Archon) is part but it likely spreads laterally when 
                          heated or fluxed, rather than delaminating or sinking. 
                          This depleted layer or region may be the FOZO source 
                          of high 3He/4He ratios (because 
                          of the low U and Th content). The lower crustal (>50-km) 
                          garnet pyroxenite, "eclogite" or piclogite 
                          mafic root is more likely to sink, because of its intrinsically 
                          high density. There are two schools of thought. Many 
                          people think in terms of Rayleigh-Taylor instabilities 
                          and gravitational instabilities and it is fine to remove 
                          delamination from their lexicon so it can be used more 
                          appropriately. Much of the so-called delamination literature 
                          also involves lithosphere rather than crust. [Ed: Click 
                          here 
                          to visit a webpage that clarifies terms]. Kay, R. W., 
                          and S. M. Kay (1993, Delamination and delamination magmatism, 
                          Tectonophysics, 219, 177-189) first started the lower 
                          continental crust delamination story and this is how 
                          others think about it. It may not be a gravity or fluid 
                          dynamic instability, as modeled by some workers.So, there are two issues; lower crust (garnet pyroxenite) 
                          vs ‘lithosphere’, or shallow mantle layer 
                          (intrinsically buoyant but cold peridotite) and gravity 
                          instability vs tectonic removal (erosion, scraping, 
                          faulting, detaching, peeling, unzipping). Confusion 
                          concerning these terms is widespread.
 I suggest that ‘crustal delamination’ 
                          or ‘delamination’ be used in the sense of 
                          Kay and Kay (1993) for removal, by whatever mechanism, 
                          of the lower continental crust. Discussions of the removal 
                          or thinning of the mantle part of the section usually 
                          involves a specific mechanism that does not fit into 
                          most definitions of the word ‘delamination’ 
                          (see Google and Google Images, for ‘delamination’). 
                          I have avoided using the word ‘lithosphere’ 
                          in this paragraph until now because ‘lithosphere’ 
                          means ‘strong shell’ and has no density 
                          or chemical connotation. The term ’perisphere’ 
                          was introduced for the refractory buoyant mantle layer; 
                          it has no connotation of strength. ‘Archon’ 
                          is the long-lived mantle root of cratons; it probably 
                          survives because it is cold, strong, buoyant and hav 
                          not been exposed to high stresses. 
 last updated 3rd 
                      May, 2018 |